Issue 3, 2019

The lithium–water configuration encapsulated by uranyl peroxide cage cluster U24

Abstract

Li and H2O encapsulated in the uranyl peroxide cage cluster U24 at 110 K are in square pyramidal and octahedral coordination environments, as dictated by the symmetry and topology of U24, in contrast to Li cations between the cages that are tetrahedrally coordinated by H2O. The ordered distribution of Li found here deviates from earlier studies at higher temperatures that reported a dynamic distribution.

Graphical abstract: The lithium–water configuration encapsulated by uranyl peroxide cage cluster U24

Supplementary files

Article information

Article type
Communication
Submitted
16 Oct 2018
Accepted
30 Nov 2018
First published
03 Dec 2018

CrystEngComm, 2019,21, 390-393

Author version available

The lithium–water configuration encapsulated by uranyl peroxide cage cluster U24

H. Traustason, S. M. Aksenov and P. C. Burns, CrystEngComm, 2019, 21, 390 DOI: 10.1039/C8CE01774C

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