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Issue 35, 2018
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More versatility than thought: large {Zr26} oxocarboxylate cluster by corner-sharing of standard octahedral subunits

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Abstract

The largest known zirconium cluster with an idealized formula of [Zr26O18(OH)30(HCOO)38] was obtained via solvolysis of ZrOCl2 in DMF/HCOOH. The observed Image ID:c8ce01064a-t1.gif{Zr6} structural organization suggests generalization, with an outlook for even larger clusters promising in the context of organo–inorganic composites and porous materials including MOFs.

Graphical abstract: More versatility than thought: large {Zr26} oxocarboxylate cluster by corner-sharing of standard octahedral subunits

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Publication details

The article was received on 28 Jun 2018, accepted on 15 Aug 2018 and first published on 15 Aug 2018


Article type: Communication
DOI: 10.1039/C8CE01064A
Citation: CrystEngComm, 2018,20, 5132-5136

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    More versatility than thought: large {Zr26} oxocarboxylate cluster by corner-sharing of standard octahedral subunits

    B. Nateghi, I. Boldog, K. V. Domasevitch and C. Janiak, CrystEngComm, 2018, 20, 5132
    DOI: 10.1039/C8CE01064A

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