Jump to main content
Jump to site search

Issue 5, 2017
Previous Article Next Article

Crystal structure and magnetic properties of two manganese(ii) homometallic coordination polymers

Author affiliations

Abstract

Two manganese(II) homometallic coordination polymers of compositions [Mn(CN)2(pz)]n (1) and {[Mn4(CN)8(bpy)3(EtOH)1.14(H2O)0.86]·bpy}n (2) have been synthesized in an inert atmosphere. In these compounds, metal cyanide 2D layers are linked into 3D networks by pillar ligands. Antiferromagnetic coupling occurs between Mn(II) ions and the antiferromagnetic ordering in these compounds is observed with Neel temperatures (TN) of 20.0 K in complex 1 and 8.0 K in complex 2.

Graphical abstract: Crystal structure and magnetic properties of two manganese(ii) homometallic coordination polymers

Back to tab navigation

Supplementary files

Article information


Submitted
15 Oct 2016
Accepted
20 Dec 2016
First published
20 Dec 2016

CrystEngComm, 2017,19, 811-816
Article type
Paper

Crystal structure and magnetic properties of two manganese(II) homometallic coordination polymers

B. Xia, K. Wang, Q. Wang, Y. Ma, Y. Tong and D. Liao, CrystEngComm, 2017, 19, 811
DOI: 10.1039/C6CE02178F

Social activity

Search articles by author

Spotlight

Advertisements