Issue 5, 2017

Novel 3-D interpenetrated metal–organometallic networks based on self-assembled Zn(ii)/Cu(ii) from 1,1′-ferrocenedicarboxylic acid and 4,4′-bipyridine

Abstract

The first examples of 3-D metal–organometallic networks (MOMNs) bearing 1,1′-ferrocenyldicarboxylate ligands have been obtained. These MOMNs exhibit a diamondoid-like network topology with 3-fold interpenetration described with point symbols for a net with loops, {66}{6}2. Their electrochemical properties were evaluated by solution-state differential pulse voltammetry.

Graphical abstract: Novel 3-D interpenetrated metal–organometallic networks based on self-assembled Zn(ii)/Cu(ii) from 1,1′-ferrocenedicarboxylic acid and 4,4′-bipyridine

Supplementary files

Article information

Article type
Communication
Submitted
02 Oct 2016
Accepted
09 Oct 2016
First published
10 Oct 2016

CrystEngComm, 2017,19, 758-761

Novel 3-D interpenetrated metal–organometallic networks based on self-assembled Zn(II)/Cu(II) from 1,1′-ferrocenedicarboxylic acid and 4,4′-bipyridine

M. L. Ospina-Castro, A. Reiber, G. Jorge, E. E. Ávila and A. Briceño, CrystEngComm, 2017, 19, 758 DOI: 10.1039/C6CE02109C

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