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Issue 41, 2016
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A microporous europium–organic framework anchored with open –COOH groups for selective cation sensing

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Abstract

[Eu2(BPTC)(H2BPTC)(DMF)4]·Guest (BMM-7) is a new 3-dimensional microporous metal–organic framework based on a functional [Eu2(COO)6(DMF)2] secondary building unit, which is rendered with uncoordinated carboxylate groups protruding into the channels. The microporous nature is confirmed using nitrogen isotherms at 77 Kelvin and the open –COOH groups can effectively and selectively capture Cu(II) cations in the exchange process.

Graphical abstract: A microporous europium–organic framework anchored with open –COOH groups for selective cation sensing

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Publication details

The article was received on 18 Aug 2016, accepted on 19 Sep 2016 and first published on 19 Sep 2016


Article type: Communication
DOI: 10.1039/C6CE01801G
CrystEngComm, 2016,18, 7955-7958

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    A microporous europium–organic framework anchored with open –COOH groups for selective cation sensing

    J. Qian, P. Yu and S. Huang, CrystEngComm, 2016, 18, 7955
    DOI: 10.1039/C6CE01801G

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