Issue 16, 2016
From the journal:

CrystEngComm

Trimeric hexa-dimethyltin-functionalized selenotungstate [{Sn(CH3)2(CH3COO)}3{Sn(CH3)2}3{Se2W18O62(OH)(H2O)}3]18−†

Wei-Chao Chen,a   Chao Qin,a   Xin-Long Wang,*a   Cai-Xia Wu,a   Yang-Guang Li,a   Hong-Ying Zang,a   Kui-Zhan Shao,a   Zhong-Min Su*a  and  En-Bo Wanga  

* Corresponding authors

a Institute of Functional Materials Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, PR China
E-mail: wangxl824@nenu.edu.cn, zmsu@nenu.edu.cn

Abstract

The trimeric organic–inorganic hybrid selenotungstate(IV) [{Sn(CH3)2(CH3COO)}3{Sn(CH3)2}3{Se2W18O62(OH)(H2O)}3]18− is composed of three Wells–Dawson-type {α-Se2W18} fragments and six {(CH3)2Sn2+} groups involving the first reported carboxyl-modified dimethyltin moieties, exhibiting photocatalytic H2 evolution activity.

Graphical abstract: Trimeric hexa-dimethyltin-functionalized selenotungstate [{Sn(CH3)2(CH3COO)}3{Sn(CH3)2}3{Se2W18O62(OH)(H2O)}3]18−

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Article information

DOI
https://doi.org/10.1039/C6CE00377J
Article type
Communication
Submitted
15 Feb 2016
Accepted
14 Mar 2016
First published
15 Mar 2016

CrystEngComm, 2016,18, 2820-2824

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Trimeric hexa-dimethyltin-functionalized selenotungstate [{Sn(CH3)2(CH3COO)}3{Sn(CH3)2}3{Se2W18O62(OH)(H2O)}3]18−

W. Chen, C. Qin, X. Wang, C. Wu, Y. Li, H. Zang, K. Shao, Z. Su and E. Wang, CrystEngComm, 2016, 18, 2820 DOI: 10.1039/C6CE00377J

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