The heterostructured biomimetic materials of calcite microcrystals covered with aragonite nanowires, as well as aragonite fibers decorated with small calcite tips, were first synthesized in a cationic polyelectrolyte mineral solution. The polymorph switching in the same microstructures shows the close relationship with thermodynamic and kinetic reaction control.
J. Zhu, L. Huang, M. Cui and L. Ma, CrystEngComm, 2015, 17, 1010 DOI: 10.1039/C4CE02002B
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