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Issue 29, 2014
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Cluster-based networks: assembly of a (4,4) layer and a rare T-shaped bilayer from [MnIII2MnII4O2(RCOO)10] coordination clusters

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Abstract

The assembly of charge-neutral mixed-valent coordination clusters [MnIII2MnII4O2(RCOO)10] (R = CHMe2, CMe3) and rigid isonicotinamide or semi-rigid aldrithiol-4 exo-bridging ligands results in (4,4) layers and a 2D bilayer containing an unprecedented type of cluster-based ‘T-shaped’ motif.

Graphical abstract: Cluster-based networks: assembly of a (4,4) layer and a rare T-shaped bilayer from [MnIII2MnII4O2(RCOO)10] coordination clusters

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Publication details

The article was received on 10 Mar 2014, accepted on 05 Jun 2014 and first published on 05 Jun 2014


Article type: Communication
DOI: 10.1039/C4CE00504J
Citation: CrystEngComm, 2014,16, 6523-6525
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    Cluster-based networks: assembly of a (4,4) layer and a rare T-shaped bilayer from [MnIII2MnII4O2(RCOO)10] coordination clusters

    I. L. Malaestean, A. Ellern, J. van Leusen, V. C. Kravtsov, P. Kögerler and S. G. Baca, CrystEngComm, 2014, 16, 6523
    DOI: 10.1039/C4CE00504J

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