Solid-state coexistence of {Zr12} and {Zr6} zirconium oxocarboxylate clusters

Iurie L. Malaestean; Meliha Kutluca Alıcı; Claire Besson; Arkady Ellern; Paul Kögerler

doi:10.1039/C3CE41829D

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Solid-state coexistence of {Zr₁₂} and {Zr₆} zirconium oxocarboxylate clusters†

Iurie L. Malaestean,^a Meliha Kutluca Alıcı,^a Claire Besson,^a Arkady Ellern^b and Paul Kögerler*^a

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* Corresponding authors

^a Institute of Inorganic Chemistry, RWTH Aachen University, 52074 Aachen, Germany
E-mail: paul.koegerler@ac.rwth-aachen.de
Fax: +49 241 80 92642

^b Ames Laboratory, Iowa State University, Ames, IA 50011, USA

Abstract

Ligand metathesis, Co(II) coordination, and partial condensation reactions of an archetypal {Zr₆} zirconium oxocarboxylate cluster result in the first example of the coexistence of the distinct zirconium oxide frameworks {Zr₆O₈} and {Zr₁₂O₂₂}. Even minor modifications to the reaction conditions push this apparent equilibrium towards the {Zr₆O₈}-based product.

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Article information

DOI: https://doi.org/10.1039/C3CE41829D
Article type: Communication
Submitted: 10 Sep 2013
Accepted: 30 Oct 2013
First published: 30 Oct 2013
This article is Open Access

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CrystEngComm, 2014,16, 43-46

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Solid-state coexistence of {Zr₁₂} and {Zr₆} zirconium oxocarboxylate clusters

I. L. Malaestean, M. K. Alıcı, C. Besson, A. Ellern and P. Kögerler, CrystEngComm, 2014, 16, 43 DOI: 10.1039/C3CE41829D

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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