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Issue 45, 2013
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Morphological diversity of Mn(III) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

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Abstract

A series of narrowly dispersed nano- and microsized CPAs has been prepared from a (porphyrin)Mn(III) biscarboxylic acid and Co(OAc)2. The morphologies have been diversified from amorphous spheres to crystalline cubes by varying reaction periods. In addition, their heterogeneous catalytic olefin oxidations are successfully demonstrated.

Graphical abstract: Morphological diversity of Mn(iii) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

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Publication details

The article was received on 09 Jun 2013, accepted on 24 Aug 2013 and first published on 29 Aug 2013


Article type: Communication
DOI: 10.1039/C3CE41072B
CrystEngComm, 2013,15, 9360-9363

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    Morphological diversity of Mn(III) metalloporphyrin-based nano- and microsized CPAs assembled via kinetic and thermodynamic controls and their application in heterogeneous catalysis

    K. Y. Lee, Y. S. Lee, S. Kim, H. M. Ha, S. Bae, S. Huh, H. G. Jang and S. J. Lee, CrystEngComm, 2013, 15, 9360
    DOI: 10.1039/C3CE41072B

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