Issue 44, 2013

Anion-controlled formation of two silver lamella frameworks based on in situ ligand reaction

Abstract

Two 2D silver lamella frameworks, [Ag4(C5H4NS)2(NO3)2]n (1) and [Ag3(C5H4NS)2]n·nClO4 (2) based on binuclear units have been solvothermally synthesized. The C5H4NS ligand was in situ generated from the cleavage of bis(2,4,6-trimethyl-3,5-bis((pyridin-2-ylthio)methyl)phenyl)methane (bmpm). Furthermore, the formation of 1 and 2 was also controlled by anions involved in the reaction. Short Ag–Ag interactions were also found in 1 and 2.

Graphical abstract: Anion-controlled formation of two silver lamella frameworks based on in situ ligand reaction

Supplementary files

Article information

Article type
Paper
Submitted
08 May 2013
Accepted
27 Aug 2013
First published
28 Aug 2013

CrystEngComm, 2013,15, 8877-8880

Anion-controlled formation of two silver lamella frameworks based on in situ ligand reaction

Z. Chen, L. Zhang, F. Liu, R. Wang and D. Sun, CrystEngComm, 2013, 15, 8877 DOI: 10.1039/C3CE40809D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements