The reaction behavior of carbon fibers and TaC at high temperatures

Abstract

Chopped carbon fibers (CFs) and TaC particles were dispersed uniformly and then sintered at temperatures of 1773, 2123, 2298, 2473 and 2823 K, respectively. The effect of sintering temperature on the microstructure of CFs was investigated. The results showed that the reaction between CFs and TaC particles was controlled by solid diffusion. When the temperature was lower than 1773 K, mainly carbon diffused into TaC. However, Ta diffused into the CFs while carbon diffused into TaC particles and then precipitated as graphite when the sintering temperature was above 2123 K. During the process, the structure of TaC was not influenced. The preferential crystalline orientation of the graphite precipitated from TaC particles increased with the increase of sintering temperature. The R value determined by Raman spectra decreased from 0.12 to 0 as the temperature increased from 2123 to 2823 K, meaning the formation of perfect graphite crystallites.