Issue 5, 2013

Distinct interpenetrated metal–organic frameworks constructed from crown ether-based strut analogue

Abstract

Rigid struts containing crown ether units (benzo-12-crown-4 and benzo-15-crown-5) coordinate with Zn4O(CO2)6 clusters, affording two different interpenetrated metal–organic frameworks (MOFs), i.e., benzo-12-crown-4-based MOF presents a “close contact” interpenetration mode, while the benzo-15-crown-5-based one has a “body center” interpenetration mode.

Graphical abstract: Distinct interpenetrated metal–organic frameworks constructed from crown ether-based strut analogue

Supplementary files

Article information

Article type
Communication
Submitted
30 Aug 2012
Accepted
19 Nov 2012
First published
19 Nov 2012

CrystEngComm, 2013,15, 841-844

Distinct interpenetrated metal–organic frameworks constructed from crown ether-based strut analogue

L. Liu, X. Wang, Q. Zhang, Q. Li and Y. Zhao, CrystEngComm, 2013, 15, 841 DOI: 10.1039/C2CE26401C

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