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Issue 1, 2013
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Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs

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Abstract

Two new isomeric bis-cyanoximes were synthesized and characterized by a variety of spectroscopic methods including UV-visible, infrared, NMR, pKa measurements and X-ray analysis. These synthesized compounds represent the first non-chelating bis-cyanoximes that can function as building blocks for new MOF-like structures.

Graphical abstract: Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs

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Publication details

The article was received on 30 Aug 2012, accepted on 12 Oct 2012 and first published on 16 Oct 2012


Article type: Paper
DOI: 10.1039/C2CE26395E
CrystEngComm, 2013,15, 152-159

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    Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs

    S. Curtis, O. Ilkun, A. Brown, S. Silchenko and N. Gerasimchuk, CrystEngComm, 2013, 15, 152
    DOI: 10.1039/C2CE26395E

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