Issue 23, 2012
From the journal:

CrystEngComm

N-oxide-4,4′-bipyridine, a forgotten ligand in coordination chemistry: structure–photoluminescence property relationships in 2D and 1D lead-coordination polymers†

Oksana Toma,a   Nicolas Mercier,*a   Mathilde Bouillanda  and  Magali Allaina  

* Corresponding authors

a MOLTECH-Anjou, UMR-CNRS 6200, 2 Bd Lavoisier, Angers, France
E-mail: nicolas.mercier@univ-angers.fr
Fax: +33 (2) 41 73 54 05
Tel: +33 (2) 41 73 50 83

Abstract

In the strong orange luminescent material of [Pb(bp4mo)Cl2], two different types of octahedra, namely PbCl4N2 and PbCl4O2, are bridged by the N-oxide-4,4′-bipyridine (bp4mo) ligand, while its protonated form, Hbp4mo+, coordinates to Pb2+ center only with the N-oxide group in [Pb(Hbp4mo)2Cl2](NO3)2. Important relationships between structures and luminescence properties are revealed.

Graphical abstract: N-oxide-4,4′-bipyridine, a forgotten ligand in coordination chemistry: structure–photoluminescence property relationships in 2D and 1D lead-coordination polymers

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Article information

DOI
https://doi.org/10.1039/C2CE26237A
Article type
Communication
Submitted
02 Aug 2012
Accepted
31 Aug 2012
First published
03 Sep 2012

CrystEngComm, 2012,14, 7844-7847

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N-oxide-4,4′-bipyridine, a forgotten ligand in coordination chemistry: structure–photoluminescence property relationships in 2D and 1D lead-coordination polymers

O. Toma, N. Mercier, M. Bouilland and M. Allain, CrystEngComm, 2012, 14, 7844 DOI: 10.1039/C2CE26237A

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