Two novel complexes based on hexagonal-planar {Co6} and rhombic {Zn4} clusters with different eight-connected topologies

Nan Wang; Jian-Gong Ma; Wei Shi; Peng Cheng

doi:10.1039/C2CE25224D

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Two novel complexes based on hexagonal-planar {Co₆} and rhombic {Zn₄} clusters with different eight-connected topologies†

Nan Wang,^a Jian-Gong Ma,^a Wei Shi^a and Peng Cheng*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry, MOE, and TKL of Metal and Molecule Based Material Chemistry, Nankai University, Tianjin 300071, China
E-mail: pcheng@nankai.edu.cn.
Fax: +86-22-23502458

Abstract

Two rare eight-connected coordination frameworks were obtained which displayed a bcu-type net constructed from hexagonal-planar {Co₆} clusters and a hex-like net constructed from rhombic {Zn₄} clusters as nodes with bis-triazole as spacers, respectively.

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Article information

DOI: https://doi.org/10.1039/C2CE25224D
Article type: Paper
Submitted: 16 Feb 2012
Accepted: 30 May 2012
First published: 31 May 2012

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CrystEngComm, 2012,14, 5634-5638

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Two novel complexes based on hexagonal-planar {Co₆} and rhombic {Zn₄} clusters with different eight-connected topologies

N. Wang, J. Ma, W. Shi and P. Cheng, CrystEngComm, 2012, 14, 5634 DOI: 10.1039/C2CE25224D

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