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Issue 12, 2012
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A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

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Abstract

A vanadyl(monocatecholate)-decorated metal-organic framework was synthesized using two sequential post-synthesis modifications. This material is catalytically active for the oxidation of organo-sulfide. In contrast to the homogeneous control catalyst, it can be tuned to be selective for the sulfoxide product using tert-butyl hydroperoxide as oxidant.

Graphical abstract: A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

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Supplementary files

Article information


Submitted
13 Dec 2011
Accepted
29 Feb 2012
First published
01 Mar 2012

CrystEngComm, 2012,14, 4115-4118
Article type
Communication

A catalytically active vanadyl(catecholate)-decorated metal organic framework via post-synthesis modifications

H. G. T. Nguyen, M. H. Weston, O. K. Farha, J. T. Hupp and S. T. Nguyen, CrystEngComm, 2012, 14, 4115
DOI: 10.1039/C2CE06666A

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