Issue 3, 2012
From the journal:

CrystEngComm

New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation†

Ricarda Berger,a   Jürg Hauser,a   Gaël Labat,a   Edwin Weberb  and  Jürg Hulliger*a  

* Corresponding authors

a Department of Chemistry and Biochemistry, University of Berne, Freiestrasse 3, Berne, Switzerland
E-mail: juerg.hulliger@iac.unibe.ch
Fax: +41 31 631 4244
Tel: +41 31 631 4241

b Institute of Organic Chemistry, TU Bergakademie Freiberg, Leipziger Strasse 29, Freiberg, Germany
Tel: +49 3731 39 23 86

Abstract

A new synthetic procedure for the production of symmetrically substituted 1,3,5-triazines by cyclization from aromatic nitriles in the molten state with zinc chloride as a catalyst has been developed and applied for a number of aromatic and fluoro aromatic nitriles. The new triazine 8 [2,4,6-tris(4′-bromobiphenylyl)-1,3,5-triazine] is shown to form channel-type inclusion compounds with several aromatic solvents, featuring two different channels in the same crystal.

Graphical abstract: New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation

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Article information

DOI
https://doi.org/10.1039/C2CE06034E
Article type
Communication
Submitted
10 Aug 2011
Accepted
21 Nov 2011
First published
08 Dec 2011

CrystEngComm, 2012,14, 768-770

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New symmetrically substituted 1,3,5-triazines as host compounds for channel-type inclusion formation

R. Berger, J. Hauser, G. Labat, E. Weber and J. Hulliger, CrystEngComm, 2012, 14, 768 DOI: 10.1039/C2CE06034E

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