Issue 2, 2012
From the journal:

CrystEngComm

3D → 3D interpenetrated and 2D → 3D polycatenated Ag(i) networks constructed from 1,4-bis(2-methylimidazol-1-ylmethyl)benzene and dicarboxylates†

Fu-Jing Liu,‡a   Di Sun,‡*b   Hong-Jun Hao,a   Rong-Bin Huang*a  and  Lan-Sun Zhenga  

* Corresponding authors

a State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, China
E-mail: rbhuang@xmu.edu.cn
Fax: +86-592-2183047

b School of Chemistry and Chemical Engineering, Shandong University, Jinan, Shandong, China
E-mail: dsun@sdu.edu.cn
Fax: +86-531-88364218

Abstract

Two novel entangled Ag(I) metal–organic frameworks (MOFs), namely [Ag2(bmimb)1.5(pzdc)·3H2O]n (1) and [Ag(bmimb)(mac)0.5·0.5H2O]n (2) (bmimb = 1,4-bis(2-methylimidazol-1-ylmethyl)benzene, H2pzdc = pyrazine-2,3-dicarboxylic acid, H2mac = L-malic acid), exhibit 3D → 3D interpenetrated and 2D → 3D polycatenated motifs, respectively, which were modulated by auxiliary dicarboxylates. Moreover, the UV-Vis spectra, thermal stabilities and photoluminescent properties were also discussed.

Graphical abstract: 3D → 3D interpenetrated and 2D → 3D polycatenated Ag(i) networks constructed from 1,4-bis(2-methylimidazol-1-ylmethyl)benzene and dicarboxylates

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Article information

DOI
https://doi.org/10.1039/C1CE06356A
Article type
Communication
Submitted
12 Oct 2011
Accepted
31 Oct 2011
First published
16 Nov 2011

CrystEngComm, 2012,14, 379-382

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3D → 3D interpenetrated and 2D → 3D polycatenated Ag(I) networks constructed from 1,4-bis(2-methylimidazol-1-ylmethyl)benzene and dicarboxylates

F. Liu, D. Sun, H. Hao, R. Huang and L. Zheng, CrystEngComm, 2012, 14, 379 DOI: 10.1039/C1CE06356A

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