Jump to main content
Jump to site search

Issue 3, 2012
Previous Article Next Article

Dryness sensitive porous 3d–4f metal–organic framework with unusual dynamic behaviour

Author affiliations

Abstract

A new three-dimensional heteronuclear metal–organic framework has been synthesized using the 1,2,4,5-benzenetetracarboxylate ligand as a linker and Pr(III)–Cu(II) dinuclear units as nodes. The resulting structure shows an unexpected dynamic behaviour, where the volume of the crystal structure is shrunk by 11.5% in a dryness atmosphere.

Graphical abstract: Dryness sensitive porous 3d–4f metal–organic framework with unusual dynamic behaviour

Back to tab navigation

Supplementary files

Publication details

The article was received on 15 Sep 2011, accepted on 17 Nov 2011 and first published on 07 Dec 2011


Article type: Communication
DOI: 10.1039/C1CE06210G
Citation: CrystEngComm, 2012,14, 765-767

  •   Request permissions

    Dryness sensitive porous 3d–4f metal–organic framework with unusual dynamic behaviour

    O. Fabelo, L. Cañadillas-Delgado, J. Pasán, P. Díaz-Gallifa, A. Labrador and C. Ruiz-Pérez, CrystEngComm, 2012, 14, 765
    DOI: 10.1039/C1CE06210G

Search articles by author

Spotlight

Advertisements