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Issue 1, 2012
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Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand

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Abstract

Three-dimensional chiral (10,3)-c MOFs are generated via symmetry breaking from achiral precursors, 5-(pyridine-3-yl)isophthalic acid and M2+ (M = Cd, Zn, Mn), and chiral transmission from molecular axially chiral conformations to framework chirality is established.

Graphical abstract: Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand

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Publication details

The article was received on 03 Aug 2011, accepted on 13 Oct 2011 and first published on 03 Nov 2011


Article type: Communication
DOI: 10.1039/C1CE05995E
CrystEngComm, 2012,14, 63-66

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    Axially chiral metal–organic frameworks produced from spontaneous resolution with an achiral pyridyl dicarboxylate ligand

    X. Tan, J. Zhan, J. Zhang, L. Jiang, M. Pan and C. Su, CrystEngComm, 2012, 14, 63
    DOI: 10.1039/C1CE05995E

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