Supramolecular isomers: the first 3-fold interpenetrating 8-connected hex-c3 net and an unusual 4-fold interpenetrating 65.8 net

Jin Yang; Jian-Fang Ma; Stuart R. Batten; Seik Weng Ng; Ying-Ying Liu

doi:10.1039/C1CE05775H

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Supramolecular isomers: the first 3-fold interpenetrating 8-connected hex-c3 net and an unusual 4-fold interpenetrating 6⁵.8 net†

Jin Yang,^a Jian-Fang Ma,*^a Stuart R. Batten,*^b Seik Weng Ng^c and Ying-Ying Liu^a

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* Corresponding authors

^a Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun, People's Republic of China
E-mail: jianfangma@yahoo.com.cn
Fax: +86 431 85098620
Tel: +86 431 85098620

^b School of Chemistry, Monash University, Victoria, Australia
E-mail: stuart.batten@sci.monash.edu.au
Fax: +61-3-9905-4597

^c Department of Chemistry, University of Malaya, Kuala Lumpur, Malaysia

Abstract

An unusual case of supramolecular isomers has been synthesized and characterized, where the α structure represents the first example of 3-fold interpenetrating 8-connected hex-c3 nets in MOFs and the β phase displays 4-fold interpenetration of a new 6⁵.8 topology.

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Article information

DOI: https://doi.org/10.1039/C1CE05775H
Article type: Communication
Submitted: 25 Apr 2011
Accepted: 24 Jun 2011
First published: 13 Jul 2011

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CrystEngComm, 2011,13, 5296-5298

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Supramolecular isomers: the first 3-fold interpenetrating 8-connected hex-c3 net and an unusual 4-fold interpenetrating 6⁵.8 net

J. Yang, J. Ma, S. R. Batten, S. W. Ng and Y. Liu, CrystEngComm, 2011, 13, 5296 DOI: 10.1039/C1CE05775H

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