Issue 10, 2011
From the journal:

CrystEngComm

Porous supramolecular compound based on paddle-wheel shaped copper(ii)–adenine dinuclear entities†

J. Thomas-Gipson,a   G. Beobide,a   O. Castillo,*a   J. Cepeda,a   A. Luque,a   S. Pérez-Yáñez,a   A. T. Aguayob  and  P. Romána  

* Corresponding authors

a Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apartado 644, Bilbao, Spain
E-mail: oscar.castillo@ehu.es

b Departamento de Ingeniería Química, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apartado 644, Bilbao, Spain

Abstract

The reaction between CuCl2 and adenine in a non-aqueous solvent provides a 3D porous structure based on paddle-wheel [Cu2(µ-adenine)4Cl2]2+ cations and Cl− anions that are held together by a robust supramolecular hydrogen bonding network. The desolvated compound is able to host different guest molecules within the ∼6 Å diameter 1D channels.

Graphical abstract: Porous supramolecular compound based on paddle-wheel shaped copper(ii)–adenine dinuclear entities

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Article information

DOI
https://doi.org/10.1039/C1CE05195D
Article type
Communication
Submitted
11 Feb 2011
Accepted
28 Feb 2011
First published
14 Mar 2011

CrystEngComm, 2011,13, 3301-3305

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Porous supramolecular compound based on paddle-wheel shaped copper(II)–adenine dinuclear entities

J. Thomas-Gipson, G. Beobide, O. Castillo, J. Cepeda, A. Luque, S. Pérez-Yáñez, A. T. Aguayo and P. Román, CrystEngComm, 2011, 13, 3301 DOI: 10.1039/C1CE05195D

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