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Issue 6, 2011
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An organic–inorganic hybrid heterobridging luminescent copper(I) polymer exhibiting thermochromic behavior

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Abstract

A 3-D organic–inorganic hybrid heterobridging copper(I) polymer {[Cu2I2(Hgtsc)]·2DMF}n (1A) (Hgtsc=glyoxal-dithiosemicarbazone) with an unusual bridging mode involving iodine and sulfur atoms has been structurally determined, which was constructed from supramolecular interactions between 2-D hybrid layers [Cu2I2(Hgtsc)]n and solvent molecules (DMF). Strong luminescence can be detected and interestingly, thermochromic behavior can be observed.

Graphical abstract: An organic–inorganic hybrid heterobridging luminescent copper(i) polymer exhibiting thermochromic behavior

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Publication details

The article was received on 04 Nov 2010, accepted on 04 Jan 2011 and first published on 20 Jan 2011


Article type: Communication
DOI: 10.1039/C0CE00754D
Citation: CrystEngComm, 2011,13, 1778-1781

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    An organic–inorganic hybrid heterobridging luminescent copper(I) polymer exhibiting thermochromic behavior

    H. Li, Y. Wang, H. Dong, Z. Chen, Y. Wu, M. Wang and S. Huang, CrystEngComm, 2011, 13, 1778
    DOI: 10.1039/C0CE00754D

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