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Issue 6, 2011
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Crystal structures of benzil monoximes controlled through configurational isomerism, molecular substitution and external complexation

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Abstract

Crystal structures of the configurational isomers of benzil monoxime (1 and 2), a p-methoxy derivative (3) and its solvated species with triethylamine (3a) are reported showing specific influences of the molecular configuration, substitution and solvation on the conformational property and packing behaviour of the molecules. Based on the observed interdependences, in particular involving modes of interaction, potential utilization of the 1,2-dione monoxime functional unit for the purpose of crystal engineering seems promising.

Graphical abstract: Crystal structures of benzil monoximes controlled through configurational isomerism, molecular substitution and external complexation

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Publication details

The article was received on 08 Sep 2010, accepted on 19 Nov 2010 and first published on 17 Dec 2010


Article type: Paper
DOI: 10.1039/C0CE00620C
CrystEngComm, 2011,13, 1931-1938

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    Crystal structures of benzil monoximes controlled through configurational isomerism, molecular substitution and external complexation

    C. Klein, C. Fischer, W. Seichter, A. Schwarzer and E. Weber, CrystEngComm, 2011, 13, 1931
    DOI: 10.1039/C0CE00620C

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