Issue 12, 2010
From the journal:

CrystEngComm

Stabilization of (SnS4)4− anion by coordinating to [TM(π-conjugated-ligand)m]n+ complex: a chain-like thiostannate(iv) {[Mn(phen)]2(SnS4)}n·nH2O exhibiting an unprecedented link mode of the (SnS4)4− anion†

Guang-Ning Liu,ab   Guo-Cong Guo,*a   Feng Chen,a   Sheng-Ping Guo,a   Xiao-Ming Jiang,a   Chen Yang,a   Ming-Sheng Wang,a   Mei-Feng Wua  and  Jin-Shun Huanga  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China
E-mail: gcguo@fjirsm.ac.cn

b Graduate school, Chinese Academy of Sciences, Beijing 100039, P. R. China

Abstract

The stabilization of the (SnS4)4− anion in the coordination of [Mn(phen)]2+ complexes brings about a novel compound {[Mn(phen)]2(SnS4)}n·nH2O (1), in which an unprecedented link mode of the (SnS4)4− anion is observed. Theoretical calculations indicate that TM complexes with big π-conjugated ligands, such as [Mn(phen)]2+, can serve as an excellent electron reservoir to stabilize the (SnS4)4− anion in 1, despite its strong condensation tendency. Magnetic measurements show the presence of strong antiferromagnetic interactions between the Mn2+ ions in 1.

Graphical abstract: Stabilization of (SnS4)4− anion by coordinating to [TM(π-conjugated-ligand)m]n+ complex: a chain-like thiostannate(iv) {[Mn(phen)]2(SnS4)}n·nH2O exhibiting an unprecedented link mode of the (SnS4)4− anion

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0CE00292E
Article type
Communication
Submitted
11 Jun 2010
Accepted
03 Aug 2010
First published
01 Sep 2010

CrystEngComm, 2010,12, 4035-4037

Permissions

Request permissions

Stabilization of (SnS4)4− anion by coordinating to [TM(π-conjugated-ligand)m]n+ complex: a chain-like thiostannate(IV) {[Mn(phen)]2(SnS4)}n·nH2O exhibiting an unprecedented link mode of the (SnS4)4− anion

G. Liu, G. Guo, F. Chen, S. Guo, X. Jiang, C. Yang, M. Wang, M. Wu and J. Huang, CrystEngComm, 2010, 12, 4035 DOI: 10.1039/C0CE00292E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements