Issue 10, 2010

Effect of lanthanide contraction on crystal structures of lanthanide coordination polymers with 2,5-piperazinedione-1,4-diacetic acid

Abstract

A series of lanthanide coordination polymers have been synthesized through the hydrothermal reaction of 2,5-piperazinedione-1,4-diacetic acid (H2PODC) and Ln(NO3)3 (Ln = La, 1; Pr, 2; Sm, 3; Ho, 4 and Er, 5). Crystal structure analysis reveals that their structural variations are attributed to the effect of lanthanide contraction.

Graphical abstract: Effect of lanthanide contraction on crystal structures of lanthanide coordination polymers with 2,5-piperazinedione-1,4-diacetic acid

Supplementary files

Article information

Article type
Communication
Submitted
25 Jan 2010
Accepted
16 Apr 2010
First published
28 May 2010

CrystEngComm, 2010,12, 2691-2694

Effect of lanthanide contraction on crystal structures of lanthanide coordination polymers with 2,5-piperazinedione-1,4-diacetic acid

G. Zhuang, X. Kong, L. Long, R. Huang and L. Zheng, CrystEngComm, 2010, 12, 2691 DOI: 10.1039/C001537G

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