Issue 7, 2010
From the journal:

CrystEngComm

A new Cu(i) coordination polymer with the CdSO4 structure type prepared via biphasic solvothermal reaction†

Tuoping Hu,ab   Haiyan He,a   Fangna Dai,a   Xiaoliang Zhaoa  and  Daofeng Sun*a  

* Corresponding authors

a Key Lab of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Shandong University, Jinan, P. R. China
E-mail: dfsun@sdu.edu.cn
Fax: +86 8836 4218
Tel: +86 8836 4218

b Department of Chemistry, North University of China, Taiyuan, Shanxi, P. R. China

Abstract

Biphasic solvothermal reaction of Cu(NO3)2·6H2O and 2,3,5,6-tetramethyl-1,4-benzenedicarboxylic acid (H2TBDC) resulted in the formation of a novel coordination polymer, [Cu(TBDC)1/2]·H2O (BPS-1). BPS-1 possesses a 3D framework containing 1D Cu(I)–COO helical chains. The use of an organic solvent with a high boiling point and an extension of the reaction time play important roles in the reduction of Cu(II) ions to Cu(I) ions and the formation of BPS-1.

Graphical abstract: A new Cu(i) coordination polymer with the CdSO4 structure type prepared via biphasic solvothermal reaction

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Article information

DOI
https://doi.org/10.1039/B919342C
Article type
Communication
Submitted
16 Sep 2009
Accepted
17 Feb 2010
First published
20 Mar 2010

CrystEngComm, 2010,12, 2018-2020

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A new Cu(I) coordination polymer with the CdSO4 structure type prepared via biphasic solvothermal reaction

T. Hu, H. He, F. Dai, X. Zhao and D. Sun, CrystEngComm, 2010, 12, 2018 DOI: 10.1039/B919342C

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