Issue 8, 2009
From the journal:

CrystEngComm

Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acidN-oxide†

Miao Du,*a   Cheng-Peng Lia  and  Jian-Hua Guoa  

* Corresponding authors

a College of Chemistry and Life Science, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin, P. R. China
E-mail: dumiao@public.tpt.tj.cn
Fax: +86-22-23766556
Tel: +86-22-23766556

Abstract

Reaction of isonicotinic acid N-oxide (HINO) with AgClO4 or AgBF4 under similar conditions unexpectedly generates two distinct crystalline products {[Ag3(INO)2(HINO)2]·(ClO4)}n (1) and {[Ag(INO)]·(H2O)}n (2). Complex 1 consists of a 3-D cationic net with mixed-connected topology and the included perchlorate counterions, whereas 2 has a 3-D neutral open framework (4-connected crb topology) with the accommodation of lattice water. The anion exchange/competition and guest desorption/adsorption behavior have also been thoroughly explored.

Graphical abstract: Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acid N-oxide

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Article information

DOI
https://doi.org/10.1039/B903074C
Article type
Communication
Submitted
16 Feb 2009
Accepted
24 Apr 2009
First published
26 May 2009

CrystEngComm, 2009,11, 1536-1540

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Unusual anion effect on the direction of three-dimensional (3-D) channel-like silver(I) coordination frameworks with isonicotinic acid N-oxide

M. Du, C. Li and J. Guo, CrystEngComm, 2009, 11, 1536 DOI: 10.1039/B903074C

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