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Issue 6, 2009
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Metal-directed assembly of two 2-D 4d–4f coordination polymers based on elliptical triple-deck cylinders hinged by meso-double helical chains

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Abstract

Two 2-D 4d–4f coordination polymers based on elliptical triple-deck cylinders hinged by meso-helical chains containing an isonicotinate ligand, namely, {[Ag2Ln(IN)4(H2O)2]·(NO3)·(H2O)}n (Ln = Sm and Eu, IN = isonicotinate), have been successfully constructed through the transformation of a single-crystal to single-crystal (SC-SC) or different metal–organic polymer units, in which the recognition between the organic ligand and two types of metal ions direct the formation of the final productions.

Graphical abstract: Metal-directed assembly of two 2-D 4d–4f coordination polymers based on elliptical triple-deck cylinders hinged by meso-double helical chains

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Article information


Submitted
05 Jan 2009
Accepted
16 Mar 2009
First published
31 Mar 2009

CrystEngComm, 2009,11, 1006-1013
Article type
Paper

Metal-directed assembly of two 2-D 4d–4f coordination polymers based on elliptical triple-deck cylinders hinged by meso-double helical chains

Y. Cai, Q. Yu, Z. Zhou, Z. Hu, H. Fang, N. Wang, Q. Zhan, L. Chen and C. Su, CrystEngComm, 2009, 11, 1006
DOI: 10.1039/B823457D

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