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Issue 1, 2009
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Inclusion of a well resolved T4(2)6(2) water tape in a H-bonded, (4,7)-binodal 3D network

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Abstract

The reaction of lanthanide nitrate with m-BDTH2 (1,3-benzeneditetrazol-5-yl) leads to a three dimensional (3D) hydrogen bonded framework formulated as {[Ln(H2O)8(m-BDTH)](m-BDT)·12(H2O)} (Ln: Ce,Nd). The topological description of the supramolecular architectures reveals a new binodal (4,7) net with a Schäfli symbol of (3.42.53)(32.42.54.65.72). A self-assembled T4(2)6(2) water tape is included and has been analyzed in comparison with known examples.

Graphical abstract: Inclusion of a well resolved T4(2)6(2) water tape in a H-bonded, (4,7)-binodal 3D network

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Publication details

The article was received on 03 Jul 2008, accepted on 19 Sep 2008 and first published on 30 Oct 2008


Article type: Paper
DOI: 10.1039/B811376A
CrystEngComm, 2009,11, 82-86

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    Inclusion of a well resolved T4(2)6(2) water tape in a H-bonded, (4,7)-binodal 3D network

    G. E. Kostakis, G. Abbas, C. E. Anson and A. K. Powell, CrystEngComm, 2009, 11, 82
    DOI: 10.1039/B811376A

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