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Issue 7, 2008
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Rare example of a polynuclear heterometallic yttrium(III)–copper(I) iodide cluster with a [Y66-O)(μ3-OH)8]8+ core structure showing single crystal-to-single crystal transformation

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Abstract

A colorless polynuclear heterometallic yttrium(III)–copper(I) iodide cluster [Y66-O)(μ3-OH)8(DMSO)16(H2O)2]8+ [Cu2I4]2−6[I] (1), isolated in a moderate yield from the hydrolytic reaction of [Y(DMSO)6(DMF)2][CuI3][I] in acetonitrile, undergoes unique crystal-to-crystal transformation to give reddish-yellow cluster [Y66-O)(μ3-OH)8(DMSO)14(H2O)4]8+ 2[CuI3]2−3[I] [I3] (2).

Graphical abstract: Rare example of a polynuclear heterometallic yttrium(III)–copper(I) iodide cluster with a [Y6(μ6-O)(μ3-OH)8]8+ core structure showing single crystal-to-single crystal transformation

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Publication details

The article was received on 12 Feb 2008, accepted on 28 Feb 2008 and first published on 25 Mar 2008


Article type: Communication
DOI: 10.1039/B802434K
CrystEngComm, 2008,10, 814-816

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    Rare example of a polynuclear heterometallic yttrium(III)–copper(I) iodide cluster with a [Y66-O)(μ3-OH)8]8+ core structure showing single crystal-to-single crystal transformation

    S. Mishra, E. Jeanneau, S. Daniele and L. G. Hubert-Pfalzgraf, CrystEngComm, 2008, 10, 814
    DOI: 10.1039/B802434K

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