Issue 5, 2008
From the journal:

CrystEngComm

Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc†

Andrew D. Burrows,*a   Mary F. Mahona  and  Claudia T. F. Wonga  

* Corresponding authors

a Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: a.d.burrows@bath.ac.uk
Fax: +44 (0)1225 386231
Tel: +44 (0)1225 386529

Abstract

[Zn4(PdCl2)2(pydc)4(H2O)4(THF)6]·3.25THF (H2pydc = 3,5-pyridinedicarboxylic acid) was formed from the reaction between Zn(NO3)2·6 H2O and trans-[PdCl2(pydc)2] in THF, and was shown by X-ray crystallography to have a three-dimensional network structure in which {PdCl2(pydc)2}4− metalloligands are linked by Zn2 centres to form a mixed-metal coordination network.

Graphical abstract: Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

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Article information

DOI
https://doi.org/10.1039/B718961C
Article type
Communication
Submitted
10 Dec 2007
Accepted
31 Jan 2008
First published
22 Feb 2008

CrystEngComm, 2008,10, 487-489

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Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

A. D. Burrows, M. F. Mahon and C. T. F. Wong, CrystEngComm, 2008, 10, 487 DOI: 10.1039/B718961C

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