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Issue 1, 2008
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Formation of a sandwich-type supercomplex through second-sphere coordination of functionalized macrocyclic polyamines

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Abstract

A novel sandwich-type supercomplex, namely {[Er(TETA)]2Er(H2O)8}NO3·10H2O (1), has been self-assembled through the conjoined hydrogen bonds by using a tetraaza-functionalized macrocyclic polyamine ligand, showing complete incorporation of the octahydrate lanthanide cation between the second coordination spheres.

Graphical abstract: Formation of a sandwich-type supercomplex through second-sphere coordination of functionalized macrocyclic polyamines

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Publication details

The article was received on 12 Jul 2007, accepted on 12 Sep 2007 and first published on 26 Sep 2007


Article type: Communication
DOI: 10.1039/B710633E
CrystEngComm, 2008,10, 19-22

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    Formation of a sandwich-type supercomplex through second-sphere coordination of functionalized macrocyclic polyamines

    X. Zhu, Z. Ma, W. Bi, Y. Wang, D. Yuan and R. Cao, CrystEngComm, 2008, 10, 19
    DOI: 10.1039/B710633E

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