Issue 11, 2007

High Z′ polymorphs have shorter C–H⋯O interactions and O–H⋯O hydrogen bonds

Abstract

The higher Z′ polymorph has a shorter C–H⋯O interaction in 26 out of 38 crystal structures with two or more forms; these data suggest the dominance of stronger hydrogen bonds, or enthalpy, in the crystallization of multiple Z′ crystal structures.

Graphical abstract: High Z′ polymorphs have shorter C–H⋯O interactions and O–H⋯O hydrogen bonds

Supplementary files

Article information

Article type
Communication
Submitted
31 Jul 2007
Accepted
02 Aug 2007
First published
22 Aug 2007

CrystEngComm, 2007,9, 980-983

High Z′ polymorphs have shorter C–H⋯O interactions and O–H⋯O hydrogen bonds

N. J. Babu and A. Nangia, CrystEngComm, 2007, 9, 980 DOI: 10.1039/B711739F

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