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Issue 9, 2007
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A three-dimensional heterocluster containing manganese clusters and hexanuclear sodium wheels

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Abstract

In this paper we report a novel heterocluster H5[Na17MnII43(PO4)36] (1), which is the first example of a crystal incorporating manganese clusters and hexametallic sodium wheels simultaneously, and these building blocks are connected to each other through phosphate groups to form a three-dimensional network. Its complicated but aesthetically pleasing architecture exhibits a perfect combination of hexamers.

Graphical abstract: A three-dimensional heterocluster containing manganese clusters and hexanuclear sodium wheels

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Article information


Submitted
17 May 2007
Accepted
13 Jun 2007
First published
13 Jul 2007

CrystEngComm, 2007,9, 740-742
Article type
Communication

A three-dimensional heterocluster containing manganese clusters and hexanuclear sodium wheels

J. Wang, D. Bi and J. Niu, CrystEngComm, 2007, 9, 740
DOI: 10.1039/B707476J

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