Variable temperature Hirshfeld surface analysis of interdigitated calix[6]arene bearing O-alkyl C18 linear chains

Thomas E. Clark; Mohamed Makha; Joshua J. McKinnon; Alexandre N. Sobolev; Mark A. Spackman; Colin L. Raston

doi:10.1039/B703166C

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Variable temperature Hirshfeld surface analysis of interdigitated calix[6]arene bearing O-alkyl C₁₈ linear chains†

Thomas E. Clark,^a Mohamed Makha,^a Joshua J. McKinnon,^a Alexandre N. Sobolev,^a Mark A. Spackman^a and Colin L. Raston*^a

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* Corresponding authors

^a Centre for Strategic Nano-Fabrication, School of Biomedical, Biomolecular and Chemical Sciences, University of Western Australia, Crawley, W.A. 6009, Australia
E-mail: clraston@chem.uwa.edu.au
Fax: +61 86488 1005
Tel: +61 86488 3045

Abstract

Calix[6]arene bearing linear C₁₈ alkyl chains crystallises in the inverted double cone conformation with three chains on either side forming a side of a hexagon in an hexagonal close packed array of interdigitated alkyl chains. The nature of the interactions has been probed over different temperatures using Hirshfeld surfaces.

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Article information

DOI: https://doi.org/10.1039/B703166C
Article type: Paper
Submitted: 01 Mar 2007
Accepted: 14 Mar 2007
First published: 26 Mar 2007

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CrystEngComm, 2007,9, 566-569

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Variable temperature Hirshfeld surface analysis of interdigitated calix[6]arene bearing O-alkyl C₁₈ linear chains

T. E. Clark, M. Makha, J. J. McKinnon, A. N. Sobolev, M. A. Spackman and C. L. Raston, CrystEngComm, 2007, 9, 566 DOI: 10.1039/B703166C

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