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Issue 10, 2006
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An unprecedented bridging [Ag2(NO3)6]4− anion as a component of an infinite silver(i) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

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Abstract

The interaction of silver(I) nitrate with the polypyridyl ligand (L) formed from two dipyridylamine units joined at their secondary amines by a 2,6-lutidinyl bridge results in a molecular ladder motif that consists of pairs of cationic [Ag2(L)MeCN]2+ units bridged by an unprecedented [Ag2(NO3)6]4− anion.

Graphical abstract: An unprecedented bridging [Ag2(NO3)6]4− anion as a component of an infinite silver(i) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

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Publication details

The article was received on 24 May 2006, accepted on 08 Aug 2006 and first published on 29 Aug 2006


Article type: Communication
DOI: 10.1039/B611270F
CrystEngComm, 2006,8, 748-750

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    An unprecedented bridging [Ag2(NO3)6]4− anion as a component of an infinite silver(I) molecular ladder incorporating a dinuclear cationic silver complex of a bis-dipyridylamine ligand

    B. Antonioli, J. K. Clegg, D. J. Bray, K. Gloe, K. Gloe, H. Heßke and L. F. Lindoy, CrystEngComm, 2006, 8, 748
    DOI: 10.1039/B611270F

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