Issue 54, 2021

Ionic additive strategy to control nucleation and generate larger single crystals of 3D covalent organic frameworks

Abstract

To generate large single crystals of 3D covalent organic frameworks, the active use of ionic additives, which can greatly impact crystal size, is proposed. The crystal size ranking was found to be in accordance with the Hofmeister series and Gutmann donor number, providing a useful strategy to enhance crystal size and, consequently, generate COF-300 single crystals of >200 μm in size.

Graphical abstract: Ionic additive strategy to control nucleation and generate larger single crystals of 3D covalent organic frameworks

Supplementary files

Article information

Article type
Communication
Submitted
07 Apr 2021
Accepted
09 Jun 2021
First published
09 Jun 2021

Chem. Commun., 2021,57, 6656-6659

Ionic additive strategy to control nucleation and generate larger single crystals of 3D covalent organic frameworks

X. Wang, R. Enomoto and Y. Murakami, Chem. Commun., 2021, 57, 6656 DOI: 10.1039/D1CC01857D

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