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Issue 41, 2021
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Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

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Abstract

Pd/Ni → Ge–F interactions supported by phosphine-chelation were found to trigger dual activation of Ge–F bonds under mild conditions. This makes fluoro germanes suitable partners for catalytic Ge–C cross-coupling and enables Germa-Suzuki reactions to be achieved for the first time.

Graphical abstract: Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

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Article information


Submitted
15 Mar 2021
Accepted
20 Apr 2021
First published
20 Apr 2021

Chem. Commun., 2021,57, 5004-5007
Article type
Communication

Pd/Ni-Catalyzed Germa-Suzuki coupling via dual Ge–F bond activation

H. Kameo, A. Mushiake, T. Isasa, H. Matsuzaka and D. Bourissou, Chem. Commun., 2021, 57, 5004
DOI: 10.1039/D1CC01392K

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