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Issue 41, 2021
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The diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene

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Abstract

The reactivity of NOBF4 towards silylene, disilene, germylene, stannylenes has been described. Smooth syntheses of compounds of composition [PhC(NtBu)2E(= O → BF3)N(SiMe3)2, E = Si (3) and Ge (4)] were accomplished from the corresponding tetrylenes. An unusual heterocycle (10) featuring B, Sn, N, P, and O atoms was obtained from the reaction with a stannylene, while a 1,2-vicinal anti addition of fluoride was observed with a disilene (12).

Graphical abstract: The diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene

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Supplementary files

Article information


Submitted
23 Feb 2021
Accepted
27 Apr 2021
First published
27 Apr 2021

Chem. Commun., 2021,57, 5008-5011
Article type
Communication

The diverse reactivity of NOBF4 towards silylene, disilene, germylene and stannylene

N. Parvin, N. Sen, P. V. Muhasina, S. Tothadi, P. Parameswaran and S. Khan, Chem. Commun., 2021, 57, 5008 DOI: 10.1039/D1CC01034D

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