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Issue 32, 2021
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Unprecedented monofunctionalized β-Anderson clusters: [R1R2C(CH2O)2MnIVW6O22]6−, a class of potential candidates for new inorganic linkers

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Abstract

Novel Anderson-type polyoxomanganotungstate clusters with the β-isomer structure, [{R1R2C(CH2O)2}MnIVW6O22]6−, were synthesized and monofunctionalized with derivatives of 1,3-propanediol via a one-pot strategy, and show unprecedented coordination activity as non-lacunary polyoxotungstate clusters and could have potential in the future construction of POM-frameworks.

Graphical abstract: Unprecedented monofunctionalized β-Anderson clusters: [R1R2C(CH2O)2MnIVW6O22]6−, a class of potential candidates for new inorganic linkers

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Supplementary files

Article information


Submitted
31 Jan 2021
Accepted
19 Mar 2021
First published
30 Mar 2021

Chem. Commun., 2021,57, 3865-3868
Article type
Communication

Unprecedented monofunctionalized β-Anderson clusters: [R1R2C(CH2O)2MnIVW6O22]6−, a class of potential candidates for new inorganic linkers

Q. Li and Y. Wei, Chem. Commun., 2021, 57, 3865
DOI: 10.1039/D1CC00563D

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