Unprecedented monofunctionalized β-Anderson clusters: [R1R2C(CH2O)2MnIVW6O22]6−, a class of potential candidates for new inorganic linkers

Qi Li; Yongge Wei

doi:10.1039/D1CC00563D

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Unprecedented monofunctionalized β-Anderson clusters: [R₁R₂C(CH₂O)₂Mn^IVW₆O₂₂]⁶⁻, a class of potential candidates for new inorganic linkers†

Qi Li

^a and Yongge Wei

*^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
E-mail: yonggewei@tsinghua.edu.cn

^b State Key Laboratory of Natural and Biomimetic Drugs, Peking University, Beijing 100191, P. R. China
E-mail: ygwei@pku.edu.cn

Abstract

Novel Anderson-type polyoxomanganotungstate clusters with the β-isomer structure, [{R₁R₂C(CH₂O)₂}Mn^IVW₆O₂₂]⁶⁻, were synthesized and monofunctionalized with derivatives of 1,3-propanediol via a one-pot strategy, and show unprecedented coordination activity as non-lacunary polyoxotungstate clusters and could have potential in the future construction of POM-frameworks.

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Article information

DOI: https://doi.org/10.1039/D1CC00563D
Article type: Communication
Submitted: 31 Jan 2021
Accepted: 19 Mar 2021
First published: 30 Mar 2021

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Chem. Commun., 2021,57, 3865-3868

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Unprecedented monofunctionalized β-Anderson clusters: [R₁R₂C(CH₂O)₂Mn^IVW₆O₂₂]⁶⁻, a class of potential candidates for new inorganic linkers

Q. Li and Y. Wei, Chem. Commun., 2021, 57, 3865 DOI: 10.1039/D1CC00563D

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Chemical Communications