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Issue 20, 2021
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Isolable small-molecule cysteine sulfenic acid

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Abstract

An isolable small-molecule cysteine sulfenic acid (Cys–SOH) protected by a molecular cradle was synthesized by direct oxidation of the corresponding cysteine thiol and its structure was established by X-ray crystallographic analysis. Studies on biologically relevant reactivity indicated its usefulness as a biorepresentative small-molecule sulfenic acid model.

Graphical abstract: Isolable small-molecule cysteine sulfenic acid

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Article information


Submitted
04 Jan 2021
Accepted
15 Feb 2021
First published
15 Feb 2021

This article is Open Access

Chem. Commun., 2021,57, 2479-2482
Article type
Communication

Isolable small-molecule cysteine sulfenic acid

T. Sano, R. Masuda, S. Sase and K. Goto, Chem. Commun., 2021, 57, 2479
DOI: 10.1039/D0CC08422K

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