Issue 19, 2021

Hypersensitive pressure-dependence of the conversion temperature of hysteretic valence tautomeric manganese–nitronyl nitroxide radical 2D-frameworks

Abstract

Valence tautomeric manganese(II)-radical lamellar compounds {[Mn2(NITIm)3]X}n with NITIm a nitronyl nitroxide radical and X = ClO4 (1) or BF4 (2) show a pressure-induced increase of their conversion temperature by approximately 40 K at a mild external pressure of 0.1 GPa, shifting the transition from near room temperature to hot temperature regions.

Graphical abstract: Hypersensitive pressure-dependence of the conversion temperature of hysteretic valence tautomeric manganese–nitronyl nitroxide radical 2D-frameworks

Supplementary files

Article information

Article type
Communication
Submitted
15 Dec 2020
Accepted
25 Jan 2021
First published
04 Feb 2021
This article is Open Access
Creative Commons BY license

Chem. Commun., 2021,57, 2376-2379

Hypersensitive pressure-dependence of the conversion temperature of hysteretic valence tautomeric manganese–nitronyl nitroxide radical 2D-frameworks

C. Lecourt, Y. Izumi, K. Maryunina, K. Inoue, N. Bélanger-Desmarais, C. Reber, C. Desroches and D. Luneau, Chem. Commun., 2021, 57, 2376 DOI: 10.1039/D0CC08144B

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