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Issue 40, 2021
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Comment on “Trimorphs of 4-bromophenyl 4-bromobenzoate. Elastic, brittle, plastic” by S. Saha and G. R. Desiraju, Chem. Commun., 2018, 54, 6348

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Abstract

A re-refinement of the published but chemically implausible, crystal structure of “Form III” of 4-bromophenyl 4-bromobenzoate shows that it is not a polymorph, but instead a co-crystal containing both 4-bromophenyl 4-bromobenzoate (≈25%) and likely 4-bromophenyl 4-nitrobenzoate (≈75%).

Graphical abstract: Comment on “Trimorphs of 4-bromophenyl 4-bromobenzoate. Elastic, brittle, plastic” by S. Saha and G. R. Desiraju, Chem. Commun., 2018, 54, 6348

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Submitted
23 Nov 2020
Accepted
01 Apr 2021
First published
19 Apr 2021

Chem. Commun., 2021,57, 4974-4975
Article type
Comment

Comment on “Trimorphs of 4-bromophenyl 4-bromobenzoate. Elastic, brittle, plastic” by S. Saha and G. R. Desiraju, Chem. Commun., 2018, 54, 6348

J. J. Whittaker, A. J. Brock, A. Grosjean, M. C. Pfrunder, J. C. McMurtrie and J. K. Clegg, Chem. Commun., 2021, 57, 4974 DOI: 10.1039/D0CC07668F

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