Issue 85, 2020
From the journal:

Chemical Communications

Ln(ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising catalysts for olefin hydrophosphination†

Ivan V. Lapshin,a   Anton V. Cherkasov, ORCID logo a   Andrey F. Asachenkob  and  Alexander A. Trifonov ORCID logo *ab  

* Corresponding authors

a Institute of Organometallic Chemistry of Russian Academy of Sciences, 49 Tropinina str., GSP-445, Nizhny Novgorod, Russia
E-mail: trif@iomc.ras.ru

b Institute of Organoelement Compounds of Russian Academy of Sciences, 28 Vavilova str., Moscow, Russia

Abstract

First Ln(II) ring-expanded NHC complexes (er-NHC)Ln[N(SiMe3)2]2 (Ln = Sm, Yb) are synthesized and proved to be highly efficient pre-catalysts for the intermolecular hydrophosphination of such indolent substrates as 1-alkenes, cyclohexene and norbornene.

Graphical abstract: Ln(ii) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising catalysts for olefin hydrophosphination

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/D0CC05424K
Article type
Communication
Submitted
09 Aug 2020
Accepted
16 Sep 2020
First published
16 Sep 2020

Chem. Commun., 2020,56, 12913-12916

Permissions

Request permissions

Ln(II) amido complexes coordinated by ring-expanded N-heterocyclic carbenes – promising catalysts for olefin hydrophosphination

I. V. Lapshin, A. V. Cherkasov, A. F. Asachenko and A. A. Trifonov, Chem. Commun., 2020, 56, 12913 DOI: 10.1039/D0CC05424K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements