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Issue 81, 2020
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Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes

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Abstract

A copper-catalyzed protoboration of borylated dendralenes is reported. The method employs an NHC–Cu catalyst and provides access to 1,4-addition products with excellent levels of chemo-, regio- and stereoselectivity. The resulting diene bis(boronates) are oxidized to the corresponding diene diols which are synthetically versatile building blocks.

Graphical abstract: Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes

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Submitted
09 Jun 2020
Accepted
08 Sep 2020
First published
08 Sep 2020

Chem. Commun., 2020,56, 12230-12233
Article type
Communication

Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes

A. Chaves-Pouso, E. Rivera-Chao and M. Fañanás-Mastral, Chem. Commun., 2020, 56, 12230
DOI: 10.1039/D0CC04018E

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