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Issue 70, 2020
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Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(ii) iodide ion-triplet complex

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Abstract

A combination of pillar[5]-bis-trithiacrown (L) and mercury(II) halides afforded a monomer complex (Cl-form), a 1-D coordination polymer (Br-form) and a supramolecular ion-triplet complex [(I·Hg·I)@L] (I-form). In the ion-triplet complex, the host encapsulates the (I–Hg2+–I) entity via Hg2+⋯π and C–H⋯I interactions, reflecting geometrical complementarity.

Graphical abstract: Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(ii) iodide ion-triplet complex

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Submitted
03 Jun 2020
Accepted
24 Jul 2020
First published
24 Jul 2020

Chem. Commun., 2020,56, 10135-10138
Article type
Communication

Metallosupramolecules of pillar[5]-bis-trithiacrown including a mercury(II) iodide ion-triplet complex

M. Shin, S. Seo, I. Park, E. Lee, Y. Habata and S. S. Lee, Chem. Commun., 2020, 56, 10135
DOI: 10.1039/D0CC03902K

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