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Issue 67, 2020
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Direct N-formylation of nitroarenes with CO2

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Abstract

Herein we describe a straightforward N-formylation of nitroarenes with CO2 to access N-aryl formamides exclusively in the presence of iron and hydrosilane as additives. This protocol showcases a good tolerance of a wide range of nitroarenes and nitroheteroarenes.

Graphical abstract: Direct N-formylation of nitroarenes with CO2

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Article information


Submitted
29 Apr 2020
Accepted
14 Jul 2020
First published
14 Jul 2020

Chem. Commun., 2020,56, 9620-9623
Article type
Communication

Direct N-formylation of nitroarenes with CO2

N. Shen, S. Zhai, C. W. Cheung and J. Ma, Chem. Commun., 2020, 56, 9620
DOI: 10.1039/D0CC03098H

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