Issue 51, 2020
From the journal:

Chemical Communications

A closed-shell monomeric rhenium(1−) anion provided by m-terphenyl isocyanide ligation†

Federico Salsi,a   Michael Neville, ORCID logo b   Myles Drance,b   Adelheid Hagenbach,a   Chinglin Chan,b   Joshua S. Figueroa ORCID logo *b  and  Ulrich Abram ORCID logo *a  

* Corresponding authors

a Freie Universität Berlin, Institute of Chemistry and Biochemistry, Fabeckstr. 34–36, 14195 Berlin, Germany
E-mail: ulrich.abram@fuberlin.de

b Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive Mail Code 0358, La Jolla, CA, USA
E-mail: jsfig@ucsd.edu

Abstract

The mixed isocyanide/carbonyl complexes cis- and trans-[Re(CO)3Br(CNArDipp2)2] (ArDipp2 = 2,6-(2,6-(i-Pr)2C6H3)2C6H3) can be synthesized from reactions of [Re(CO)5Br] and CNArDipp2 depending on the conditions applied. Reduction of the neutral Re(I) species gives the monoanionic complex [Re(CO)3(CNArDipp2)2]− or the neutral [Re(CO)3(CNArDipp2)2], which contain rhenium in the formal oxidation states “−1” and “0”, respectively.

Graphical abstract: A closed-shell monomeric rhenium(1−) anion provided by m-terphenyl isocyanide ligation

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Article information

DOI
https://doi.org/10.1039/D0CC03043K
Article type
Communication
Submitted
27 Apr 2020
Accepted
07 May 2020
First published
14 May 2020

Chem. Commun., 2020,56, 7009-7012

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A closed-shell monomeric rhenium(1−) anion provided by m-terphenyl isocyanide ligation

F. Salsi, M. Neville, M. Drance, A. Hagenbach, C. Chan, J. S. Figueroa and U. Abram, Chem. Commun., 2020, 56, 7009 DOI: 10.1039/D0CC03043K

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